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From: Keith Kaste <kkaste_at_slip.net>
subject: [Paddlewise] epoxy problems
Date: Sun, 01 Feb 1998 16:03:55 -0800
I am building a stitch and glue boat these days.  I have gotten to the
point where I am fiberglassing the hull.  The epoxy (West Systems) is
not behaving the way I remember it during the warmer months.  It is much
more viscous when I'm mixing it.  It gets really white.  I thought that
since the temperature is less, the pot time would be noticeably longer.
It is not.  Furthermore, it doesn't take long before it starts turning
my boat milky white with each stroke of my foam brush.  Does anybody
know what is causing this?  Is there a better epoxy system to be using?

Also, I'm seeing an oily film on the epoxied surface 24 hours after it
has set up.  I am assuming this is the dreaded "amine blush".  I have
not seen this phenomenon before. I used a scratch pad and water to get
it off.  That seemed to work.  Some kit companies say you don't have to
sand between coats if you don't wait longer than 2 or 3 days.  Is this
accepted practice?  Does it apply in all temperature and humidity
conditions?

Does West Systems have a web site?



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From: Dave Kruger <dkruger_at_seasurf.com>
subject: Re: [Paddlewise] epoxy problems
Date: Sun, 01 Feb 1998 17:46:15 -0800
Keith Kaste wrote:
> 
> I am building a stitch and glue boat these days.  I have gotten to the
> point where I am fiberglassing the hull.  The epoxy (West Systems) is
> not behaving the way I remember it during the warmer months.  It is much
> more viscous when I'm mixing it.  It gets really white.  I thought that
> since the temperature is less, the pot time would be noticeably longer.
> It is not.  Furthermore, it doesn't take long before it starts turning
> my boat milky white with each stroke of my foam brush.  Does anybody
> know what is causing this?  Is there a better epoxy system to be using?

The clues you give suggest that the epoxy has "separated" slightly,
owing to long storAge at a low temperature.  If the containers are
reasonably transparent, examine both hardener and resin with a strong
light behind the containers and see if you can spot any separation.  A
flashlight down the throat if you have an opaque container may do the
job, also.

If it has separated, incubate it for several hours in warm water (100F),
stirring occasionally.  It will remain well-mixed for quite a while
unless you let it get very cold again.  The best solution is to keep
both hardener and resin in a heated plywood box.  I used a 75 W light
bulb to keep such a box warm and it worked well.  For reference: I found
80 - 90 F was ideal for System 3 resin/hardener (I used
2:1::normal:fast, though fast hardener is OK to store at that
temperature).  YMMV

> Also, I'm seeing an oily film on the epoxied surface 24 hours after it
> has set up.  I am assuming this is the dreaded "amine blush".  I have
> not seen this phenomenon before. I used a scratch pad and water to get
> it off.  That seemed to work.  Some kit companies say you don't have to
> sand between coats if you don't wait longer than 2 or 3 days.  Is this
> accepted practice?  Does it apply in all temperature and humidity
> conditions?

If the blush does not disappear on clearing up the separation problem,
something else is wrong.  Check your mixing devices.  Small volumes are
notoriously difficult to measure accurately, especially if the epoxy
ingreds are cool -- they stick to the container walls badly.  Switch to
weighing the ingreds into a single container:  resin, then hardener. 
Very easy to control the mix that way.

P.S.  Keith, it may be uncool to double post to both Paddlewise and to
Wave~Length.  I suspect we should ask Jackie and Howie (thank you Alan)
about that.  Different, identical posts are probably OK, if I understand
the etiquette properly.

-- 
Dave Kruger
Astoria, OR
sea kayaker -- and chemist
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From: Dave Kruger <dkruger_at_seasurf.com>
subject: Re: [Paddlewise] epoxy problems
Date: Sun, 01 Feb 1998 17:50:55 -0800
Keith Kaste wrote:
> 
> The epoxy (West Systems) is
> not behaving the way I remember it during the warmer months.  It is much
> more viscous when I'm mixing it.  It gets really white.  I thought that
> since the temperature is less, the pot time would be noticeably longer.
> It is not.  

Forgot to comment on this.  The high viscosity is a sure sign of cold
epoxy.  The high viscosity makes mixing tough, and "whips" air into the
mix.  Even though the resin is cold to begin with, the exothermic
behavior of the mix will quickly heat it up, foaming the bubbles and
creating a hell of a mess!

Probably the white appearance is due to bubbles in the resin or maybe
"outgassing" from the wood.  Hard to tell without more info.

-- 
Dave Kruger
Astoria, OR
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From: Nick Schade <schade_at_guillemot-kayaks.com>
subject: Re: [Paddlewise] Wave~Length: epoxy problems
Date: Sun, 1 Feb 1998 22:43:22 -0500
I agree with Dave Kruger's "whipped in air" diagnosis. The high viscosity
resin is trapping air. Warming up the resin before mixing will reduce this
problem, but when it cools off again as you start spreading it on the
fiberglass, you will again force air into the resin again, making it turn
white. The oily film is probably amine blush as you say.

If you can heat your space up, you will probably have better results.
However, you want to do your glassing on falling temperatures so the any
trapped air shrinks instead of expanding. So heat up the space hot before
starting and let it cool down slowly as you work. Note that a kerosene or
propane heater produces water vapor as a result of combustion and humidity
exaserbates blushing problems.

I have had very good results with MAS epoxy. It is low viscosity and does
not blush. They now have "winter cure" which cures down to 35°. It stays
low viscosity and does not crystalize at low temperatures. NOTE: where I
work is a distributer for MAS so I am not completely unbiased, but I used
it before I started working there.
Nick

At 4:03 PM -0800 2/1/98, Keith Kaste wrote:
>I am building a stitch and glue boat these days.  I have gotten to the
>point where I am fiberglassing the hull.  The epoxy (West Systems) is
>not behaving the way I remember it during the warmer months.  It is much
>more viscous when I'm mixing it.  It gets really white.  I thought that
>since the temperature is less, the pot time would be noticeably longer.
>It is not.  Furthermore, it doesn't take long before it starts turning
>my boat milky white with each stroke of my foam brush.  Does anybody
>know what is causing this?  Is there a better epoxy system to be using?
>
>Also, I'm seeing an oily film on the epoxied surface 24 hours after it
>has set up.  I am assuming this is the dreaded "amine blush".  I have
>not seen this phenomenon before. I used a scratch pad and water to get
>it off.  That seemed to work.  Some kit companies say you don't have to
>sand between coats if you don't wait longer than 2 or 3 days.  Is this
>accepted practice?  Does it apply in all temperature and humidity
>conditions?
>
>Does West Systems have a web site?
>
>
>
>~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
>Wave~Length Paddling Mailing List
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>World Wide Web:    http://www.wie.com/~wavenet/
>~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~




Nick Schade
Guillemot Kayaks
c/o Newfound Woodworks, RFD 2 Box 850, Bristol, NH 03222
(603) 744-6872

Schade_at_guillemot-kayaks.com
http://www.guillemot-kayaks.com/

>>>>"It's not just Art, It's a Craft!"<<<<



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