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From: Dickson, Dana A. <dana.dickson_at_unisys.com>
subject: RE: [Paddlewise] Hazards of indoor kayak building.
Date: Tue, 16 Nov 1999 11:54:19 -0600
Dave basically has it right on the sensitization issue.  I have a couple of
thoughts for Kevin to consider.  First MAS has a website that has MSDSs,
Material Safety Data Sheets for their products.  The first rule is to do
what the manufacturer recommends, if you cannot understand what they are
recommending call and ask for clarification.  MAS gives inconsistent advice
on personal protection use with their products.  One of the MSDSs recommends
supplied air respirators. when working with their products.  The salesman at
the presentation I attended in Minnesota suggested a half mask with chemical
filters and particulate filters.  The MAS salesman also claims his materials
are not as sensitizing as other epoxies.  That does not fit with anything I
have ever found in the literature, so I consider the source.

The 1 square foot fan will not hurt but it won't help much either.  A tent
around the appliation area and lots of air exhaust will help improve the
protection provided by ventilation.

The MAS epoxies have components with very low vapor pressure.  As a result
the airborne exposure to vapors is not likely to get very high.  When I have
worked with epoxies and boat building I wore a full face respirator, nitrile
gloves and a Tyvek suit.  The full face respirator was to provide eye
protection as well as respiratory protection.  Gloves and Tyvek keep the
glue off of your clothes and skin.  A half mask with a multipurpose
cartridge and a particulate filter along with goggles will serve instead of
the full face respirator.

I am more concerned with exposure to the partially cured epoxy that with
airborne exposure to vapors.  The epoxy is hard to the touch long before it
is fully cured.  Some of the parts of the chemical molecules that react in
the hardner/resin reaction are still present in the hard but not fully cured
resin and can react with people.  The routes of exposure will be skin
contact and respiratory.  The personal protective gear I mention above will
help limit exposure to the sanding particles.  Keeping the sanding dust
confined will help prevent contamination in the rest of the house.

I'm curious; how do WE get pregnant?  Not that I want to go too far off
topic but, last I heard men made a contribution and women did the rest of
the pregnancy.  It has been a while since I looked at the MAS epoxy MSDSs
but I don't think there was anything there that would be particularily toxic
for pregnant women or their embryos or fetuses.  As a bit of trivia on this
the stage of pregnancy when there is the greatest risk of causing birth
defects is very early, before even the woman knows she is pregnant.  So if
you are really concerned abstain for months before building the boat.

Overall building a stitch and glue boat should not present an unreasonable
risk to you or your wife, pregnant or otherwise.  Just take some reasonable
precautions to control personal exposure and you should be fine.

Dana

> Date: Mon, 15 Nov 1999 17:25:08 -0800
> From: Dave Kruger <dkruger_at_pacifier.com>
> Subject: Re: [Paddlewise] Hazards of indoor kayak building?
<snip>
> Let me put this caveat up front:  I'm a mere organic chemist, 
> and yield to
> Paddlewiser Dana Dickson, who is a genuine industrial hygienist with
> professional training pertinent to this discussion.  I hope 
> Dana picks up on
> this thread.  What you read below stands to be improved 
> on/corrected by Dana. 
> (Thank you, Dana!)
> 
> A couple things are skewed here:
> 
> 1. The System Three resins (all epoxy-based) I have used are 
> "low" in odor,
> except for a distinct ammonia-like smell.  Unless the 
> polyamine hardener in
> West materials is chemically very different (or, impure), it 
> should also be
> relatively low-odor.  OTOH, so-called "five-minute" epoxy 
> hardeners **do**
> have a very pungent "dog-urine" odor to them.  I find them 
> very obnoxious.
> 
> The hazards with epoxy are primarily related to contact 
> dermatitis (or, if you
> do not wear a mask while sanding, inhalation reaction), 
> leading in some
> individuals to **sensitization** and subsequent severe 
> allergic reaction on
> re-exposure.  For *some* of those sensitized folks, even 
> walking into an open
> boat-building shop causes an immediate reaction.  The 
> original poster would be
> well-advised to separate his sleeping/eating area from the 
> place where he does
> his epoxy work, for this reason:  no one can predict who the 
> "sensitive"
> individuals are, and who the "insensitive"  (less-sensitive?) 
> folks are.  BTW,
> I have committed every epoxy error possible, and I am not 
> sensitized (yet?). 
> YMMV!!!
> 
> 2. Sidney has confused "epoxy" with "polyester" in his 
> original posting (see
> my [sic] notations above).  AFAIK, there are no "polyester 
> epoxy" resins.  I
> believe his "polyester epoxy" is really polyester/styrene 
> resin or possibly
> vinylester resin.  This is a very understandable error, if 
> for no other reason
> that some retailers do not distinguish the two.
> 
> Finally, any polyester/vinyl ester resin should stink up the 
> place big time,
> and IIRC, the vapors are an acute health hazard in a high enough
> concentration.  Some folks find the odor from 
> polyester/styrene or vinylester
> materials attractive (??!!).  Others are repulsed.
> 
> Dana, bail me out!
> 
> Thanks.
> 
> - -- 
> Dave Kruger
> Astoria, OR
> 
>Date: Mon, 15 Nov 1999 13:38:02 -0500 (EST)
From: Kevin Zembower <kevinz_at_charm.net>
Subject: [Paddlewise] Hazards of indoor kayak building?

I'm interested in building a plywood stitch-n-glue CLC Chesapeake 17 kayak
in my basement this winter. CLC supplies MAS epoxy with their kits. Any
ideas on whether this will be hazardous to my health or my wife's? What if
we were pregnant? I was just going to blow a 1 sq. ft. fan out the window,
but I could build a plastic sheeting enclosed booth, if recommended.

I'm interested in everyone's opinion, but I know that we have some
professionals in PW, industrial hygienists, physicians and such. Please
don't worry that, if something goes wrong, I would come back and sue you
for your casual advice. I understand that free advice is worth every penny
you pay for it.

Thank you in advance for your considered opinions.

- -Kevin Zembower


- --
  kevinz_at_charm.net      Kevin Zembower
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