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From: Dave Kruger <kdruger_at_pacifier.com>
subject: Re: [Paddlewise] Stainless Hardware (was: Cleaning fibreglass kayaks)
Date: Wed, 6 Nov 2002 19:42:22 -0800
Michael Daly" <michaeldaly_at_rogers.com> wrote:

(In response to Steve at "ACKC" <aldercreek_at_qwest.net>:)

> Stainless steel comes in quite a variety of grades.  I am sure the grade
of
> SS in your knife is quite different from the grade used in deck hardware.

>> But both the knife and the deck fittings rust.  I've yet to discover an
alloy of stainless that doesn't corrode.  There aren't many stainless
fittings on a sea kayak - a handful of nuts and bolts and a couple
of deck U bolts maybe - these may not be considered critical if there's
a thin layer of corrosion.  Rudder cables are another story - swaged
ends that have non-stainless crimps might corrode faster and could
fail if not inspected regularly.  I've noticed that some have aluminum
bits and aluminum and steel are a famously bad combination.  I've
never seen this happen, so it's conjecture on my part at this point.>>

Steve and Michael have it right:  there is stainless and there is stainless.
And, there is no grade that will not corrode ... eventually.  Salt water,
because of the chloride ions in it, is very aggressive towards iron-based
alloys, owing to complexation of the chloride with ferrous (and then ferric)
ion.

The bottom line, however, might be whether the lifetime of the fitting,
knife, or whatever, is "long enough."  In full-size marine applications, it
is good practice to pull a few fittings, especially fasteners, after four or
five years, and inspect.  Even stainless needs this sort of scrutiny because
it is particularly susceptible to "crevice corrosion" in which the corrosion
occurs in __hidden__ areas of low oxygen, where the lack of oxygen reduces
the protective oxides of chromium and allows attack of the underlying iron
in the alloy.  (I know this is counter-intuitive;  before anybody goes off
on a rant, check out the term crevice corrosion.  It is a well-documented
problem for stainless, and well-studied.)

This means that a little visible rust for through-hull fittings and deck
hardware may be a __good__ sign, inasmuch as it may mean the stainless is
still in an oxidized environment.      Note:  I said "may," and not "is
certainly."  YMMV when it comes to corrosion of stainless.

I leave the problem of maintaining a shiny stainless knife in pristine
condition to others.  For me, I am content to know that the stainless I
can't see, that holds my deck lines on, and allows my rudder to steer, is
probably in good shape.

--
Dave Kruger
Astoria, OR
longtime chemist
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From: Steve Scherrer <flatpick_at_teleport.com>
subject: Re: [Paddlewise] Stainless Hardware (was: Cleaning fibreglass kayaks)
Date: Thu, 7 Nov 2002 07:31:39 -0800
Thanks Dave!  Seems like I read that the more rust resistant SS is the
softer/ weaker the alloy.  es correcto?  hence the poor edge holding
capabilities of this *rust proof* knife.  Just found this on
http://divermag.com/archives/nov98/knives.html
>>Blades can be made from a variety of metals but the most popular is
stainless steel, either 304 or 420 grade of stainless steel alloy. The
higher the number the lower the grade of stainless steel and the better the
blade will keep an edge. A lower number means a higher grade of stainless
and the more resistant it is to rust. Some of Underwater Kinetics line of
Blue Tang and Remora knives are made of 316 grade stainless which offers a
good compromise. A few manufacturers, such as Ocean Master, make knives from
titanium which is light, very strong, keeps a good edge and is rustproof.
The only drawback is that titanium is quite a bit more expensive than
stainless steel. In any event, knives should always be rinsed thoroughly in
fresh water after every dive and dried separate from the sheath. <<



steve


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From: Dave Gorjup <dgorjup_at_cox.net>
subject: Re: [Paddlewise] Stainless Hardware (was: Cleaning fibreglass kayaks)
Date: Thu, 07 Nov 2002 11:23:08 -0500
FWIW, titanium is also much more brittle than SS. Don't use titanium knifes 
as prybars or other titanium objects in situations where there may be 
quickly incurred stress loads. ;-)
Dave G. - Poquoson Va paddler and old machinist

At 07:31 AM 11/7/2002 -0800, Steve Scherrer wrote:
>Thanks Dave!  Seems like I read that the more rust resistant SS is the
>softer/ weaker the alloy.  es correcto?  hence the poor edge holding
>capabilities of this *rust proof* knife.  Just found this on
>http://divermag.com/archives/nov98/knives.html
> >>Blades can be made from a variety of metals but the most popular is
>stainless steel, either 304 or 420 grade of stainless steel alloy. The
>higher the number the lower the grade of stainless steel and the better the
>blade will keep an edge. A lower number means a higher grade of stainless
>and the more resistant it is to rust. Some of Underwater Kinetics line of
>Blue Tang and Remora knives are made of 316 grade stainless which offers a
>good compromise. A few manufacturers, such as Ocean Master, make knives from
>titanium which is light, very strong, keeps a good edge and is rustproof.
>The only drawback is that titanium is quite a bit more expensive than
>stainless steel. In any event, knives should always be rinsed thoroughly in
>fresh water after every dive and dried separate from the sheath. <<
>
>
>
>steve


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From: Dave Kruger <kdruger_at_pacifier.com>
subject: Re: [Paddlewise] Stainless Hardware (was: Cleaning fibreglass kayaks)
Date: Thu, 7 Nov 2002 10:40:19 -0800
Couple URL's for those who want more on two of the common stainless alloys:

304 (less corrosion-resistant):  http://www.assda.asn.au/304.html

316 (more corrosion-resistant; preferred for marine applications):
http://www.assda.asn.au/316.html

--
Dave Kruger
Astoria, OR

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From: PeterO <rebyl_kayak_at_iprimus.com.au>
subject: RE: [Paddlewise] Stainless Hardware (was: Cleaning fibreglass kayaks)
Date: Fri, 8 Nov 2002 22:51:14 +1100
G'day,

Last night I bit the bullet and stopped rinsing the boat with fresh water.
Its easy to dry off all the stainless fittings (including the rudder pedals)
as we're in the middle of a drought and a very hot spell. Is there anything
worth spraying on the fittings (especially the rudder pedals) that will help
to protect against saltwater corrosion?

All the best, PeterO
(Australia)


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From: Dave Gorjup <dgorjup_at_cox.net>
subject: RE: [Paddlewise] Stainless Hardware (was: Cleaning fibreglass kayaks)
Date: Fri, 08 Nov 2002 08:09:18 -0500
At 10:51 PM 11/8/2002 +1100, PeterO wrote:
>G'day,
>
>Last night I bit the bullet and stopped rinsing the boat with fresh water.
>Its easy to dry off all the stainless fittings (including the rudder pedals)
>as we're in the middle of a drought and a very hot spell. Is there anything
>worth spraying on the fittings (especially the rudder pedals) that will help
>to protect against saltwater corrosion?
>
>All the best, PeterO
>(Australia)

Peter,
I use WD-40 spray. It displaces water and tends to leave an anti-corrosion 
film on metal. Use sparingly, it goes a long way.
Dave G.
Poquoson, Va.

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From: Dave Kruger <kdruger_at_pacifier.com>
subject: Re: [Paddlewise] Stainless Hardware (was: Cleaning fibreglass kayaks)
Date: Thu, 7 Nov 2002 11:47:40 -0800
Steve,

I don't know about that weaker/softer = more rust-resistant generalization.
I'm no metallurgist, so I'll have to plead ignorance.

Too many variables, I think.  Those URL's I posted might lead to better info
on that.  The generalization in the text you quote (that the higher the
number, the lower the grade of SS) is wrong on one count, at least:  304 is
not as corrosion-resistant as 316.  I'm not familiar with 420 SS.  Could be
the 400 series is a very different series than the 300 series.

I suspect if a person wants a truly rust-free knife, she has to get a
titanium one.

Bring lots of bucks!

--
Dave Kruger
Astoria, OR

----- Original Message -----
From: "Steve Scherrer" <flatpick_at_teleport.com>

Subject: Re: [Paddlewise] Stainless Hardware (was: Cleaning fibreglass
kayaks)


> Thanks Dave!  Seems like I read that the more rust resistant SS is the
> softer/ weaker the alloy.  es correcto?  hence the poor edge holding
> capabilities of this *rust proof* knife.  Just found this on
> http://divermag.com/archives/nov98/knives.html
> >>Blades can be made from a variety of metals but the most popular is
> stainless steel, either 304 or 420 grade of stainless steel alloy. The
> higher the number the lower the grade of stainless steel and the better
the
> blade will keep an edge. A lower number means a higher grade of stainless
> and the more resistant it is to rust. Some of Underwater Kinetics line of
> Blue Tang and Remora knives are made of 316 grade stainless which offers a
> good compromise. A few manufacturers, such as Ocean Master, make knives
from
> titanium which is light, very strong, keeps a good edge and is rustproof.
> The only drawback is that titanium is quite a bit more expensive than
> stainless steel. In any event, knives should always be rinsed thoroughly
in
> fresh water after every dive and dried separate from the sheath. <<

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