[Paddlewise] Lithium Ion Batteries are Much SaferThan Lithium Batteries

From: Dave Kruger <kdruger_at_pacifier.com>
Date: Sat, 9 Apr 2005 21:34:03 -0700
I think some inadvertent misinformation has been posted here on lithium ion 
batteries.  Lithium ion batteries do not contain metallic lithium unless they 
are severely mischarged.  Rather, it is __lithium__batteries which contain 
metallic lithium, and which are a severe fire hazard if punctured.  Lithium 
batteries are not rechargeable.

The VHF handheld radios which have been discussed here recently all use 
__lithium ion__ batteries, and are about as safe as NiCad or NiMH batteries. 
Unless they are severely mis-charged, they should not produce any metallic 
lithium and therefore are incapable of burning.  Like any rechargeable 
battery, if they are recharged extremely rapidly and allowed to overcharge, 
they may vent caustic chemicals, or generate enough heat to start a fire in 
other materials.  But, they are not themselves highly likely to catch fire.

Here is one of several links I Googled up which distinguish these two 
batteries:  http://www.allegromicro.com/techpub2/cadex/index341.htm

This distinction, between lithium (an element) and lithium ions (the combined 
form of lithium found when it interacts with other substances) is not 
generally understood by many who write "warnings" you will see on the 
Internet.  Caveat emptor.

--
Dave Kruger
Just a long-time chemist 
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Received on Sat Apr 09 2005 - 21:34:03 PDT

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