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From: Tord Eriksson <tord_at_tord.nu>
subject: Re: [Paddlewise] PaddleWise Plastic Boats
Date: Tue, 31 Jul 2007 14:15:32 +0200
On Monday 30 July 2007 19:30, Derek wrote:
> How does one assess the viability of an older plastic
> kayak?  Plastic can become brittle over time, even if
> its stored indoors.  Sunlight can make ageing even
> worse.  How do you determine how much life an older
> kayak has left?  If you have a kayak infront of you,
> how do you determine how brittle it has become?

Immersing nylon screws in boiling water recovers their strength
quite a bit - all plastics need to have a certain amount of humidity
in them, to attain maximum strength.

I would think washing the plastic kayak in fresh water, once in a while,
is one way of keeping them OK - a sunblocker, like 303 Aerospace,
can be used to block the UV, or you could paint it with a 'silver' colour, 
totally blocking light reaching the surface!

Tord

PS A combination of UV and frost kills any plastic, in the long run! The
UV cracks the surface, water enter the cracks and the frost does the rest!
This combination even kills rocks, eventually!
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From: Dave Kruger <kdruger_at_pacifier.com>
subject: Re: [Paddlewise] PaddleWise Plastic Boats
Date: Tue, 31 Jul 2007 06:51:51 -0700
Tord Eriksson wrote:

> Immersing nylon screws in boiling water recovers their strength
> quite a bit - all plastics need to have a certain amount of humidity
> in them, to attain maximum strength.

True for nylon (and, perhaps, Dacron) -- because of the polarity of the 
groups formed when it is manufactured (nylon is a polyamide; Dacron is 
polyethylene terephthalate, a polyester), which are attracted to water; 
other, nonpolar plastics such as polyethylene and polypropylene need 
refreshing of their plasticizers (small, nonpolar molecules incorporated 
into the polymer mix at manufacture) to maintain their plasticity and avoid 
embrittlement.  The differing chemical makeup of plastics accounts for 
these differences.  Not all plastics are chemically alike.

> I would think washing the plastic kayak in fresh water, once in a while,
> is one way of keeping them OK - a sunblocker, like 303 Aerospace,
> can be used to block the UV, or you could paint it with a 'silver' colour, 
> totally blocking light reaching the surface!

Washing only keeps the surface clean -- it does not extend the life of the 
boat;  however, 303 contains a common placticizer, and slows the aging 
process of rotomolded boats.  It also has a UV absorber.  Finally, some 
paints have solvents in them which may prematurely age rotomolded boats ... 
and most paints will not stick to such boats anyway.  Exception:  Krylon's 
Fusion does stick to polyethylene.

Sorry, Tord, but these false rumors need to be spiked aborning.

-- 
Dave Kruger
Astoria, OR
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From: Derek <glamourpets_at_yahoo.com>
subject: Re: [Paddlewise] PaddleWise Plastic Boats
Date: Tue, 31 Jul 2007 08:39:24 -0700 (PDT)
I was pondering this plastic lifespan issue.  It seems
to me that the "inventors" of this form of plastic
would have aggressively tested the material before
putting it into production.  They should have a pretty
good idea what the typical life expectancy is for
their product.  Does anyone have access to this sort
of laboratory data?

Derek

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From: Allan McLane <amcl_at_sover.net>
subject: Re: [Paddlewise] PaddleWise Plastic Boats
Date: Tue, 31 Jul 2007 13:12:36 -0400
On Tue, 31 Jul 2007 08:39:24 -0700 (PDT), Derek wrote:

I was pondering this plastic lifespan issue.  It seems
to me that the "inventors" of this form of plastic
would have aggressively tested the material before
putting it into production.  They should have a pretty
good idea what the typical life expectancy is for
their product.  Does anyone have access to this sort
of laboratory data?

===============

Considering the product's operating environment it's remarkable that plastic kayaks last as long as they do.

The variables are duration and degree of UV exposure, something the maker has little control over.

Try googling "polyethylene UV exposure" and you'll get a sense of the difficulty is accurately predicting product life.

--allan
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