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From: Tord Eriksson <tord_at_tord.nu>
subject: Re: [Paddlewise] Tsunami 120 vs 145
Date: Mon, 4 Dec 2006 23:01:30 +0100
On Monday 04 December 2006 15:03, Matt wrote:
> Since there are no fibers in rotomolded kayaks increasing
> their brittleness becomes a far greater problem for them than for the
> resin in a fiberglass kayak. Most of the toughness of rotomolded kayaks
> comes from their flexibility so do your best to keep them that way.

I fly some model aircraft, and they usually have their wings held in place 
with nylon bolts, and to keep them flexible, and less brittle you should
cook them at least once a season - could the same help for a rotomoulded
kayak?

Tord
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From: Darryl <Darryl.Johnson_at_sympatico.ca>
subject: Re: [Paddlewise] Tsunami 120 vs 145
Date: Mon, 04 Dec 2006 19:31:07 -0500
> On Monday 04 December 2006 15:03, Matt wrote:
> > Since there are no fibers in rotomolded kayaks increasing
> > their brittleness becomes a far greater problem for them than for the
> > resin in a fiberglass kayak. Most of the toughness of rotomolded kayaks
> > comes from their flexibility so do your best to keep them that way.
> 
> I fly some model aircraft, and they usually have their wings held in place 
> with nylon bolts, and to keep them flexible, and less brittle you should
> cook them at least once a season - could the same help for a rotomoulded
> kayak?
> 
> Tord


I guess you could find one of the many "hot springs" scattered around 
the world and go for a paddle amongst the bathers.

You could tour the world, hit a whole bunch of them and apply to the 
Guinness Book of Records.

Otherwise, it's going to one hell of a pot to get the kayak inside!

-- 
  Darryl
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From: Marilyn Kircus <mkircus_at_sbcglobal.net>
subject: Re: [Paddlewise] Nylon properties
Date: Tue, 5 Dec 2006 02:58:10 -0800 (PST)
When you really need to know, you can look up properties of whatever kind of plastic you are talking about.

Here is one citation on nylon.

http://www.dynalabcorp.com/technical_info_nylon.asp

Marilyn
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From: mike dziobak <mdziobak_at_mtu.edu>
subject: Re: [Paddlewise] Tsunami 120 vs 145
Date: Mon, 4 Dec 2006 21:08:41 -0500 (EST)
I would say no. PE nalgene bottles that I have filled with near boiling 
H2O on winter camping trips seem to become brittle and break after only a
short period of use. I have some training as a chemist but I don't see how
"cooking" a nylon bolt would keep in flexible unless nylon becomes work
hardened over time and cooking it anneals it.
-mike


>
> I fly some model aircraft, and they usually have their wings held in place
> with nylon bolts, and to keep them flexible, and less brittle you should
> cook them at least once a season - could the same help for a rotomoulded
> kayak?
>
> Tord
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From: Bart Boelryk <bart_at_kayrak.ca>
subject: [Paddlewise] boiling kayaks
Date: Mon, 04 Dec 2006 20:47:55 -0800
regarding nylon vs polyethylene:

nylon is extremely hydroscopic. meaning it absorbs a great deal of moisture.
nylon can go from peanut brittle to spaghetti based on humidity and water
absorption.
a lot of care must be taken to dry it out prior to moulding.
this is why what you did with your nylon bolts is a great idea.
besides the need for a great big pot, polyethylene does not absorb water
like nylon, so this technique would not give you the same results.

cheers

Bart

>
> I fly some model aircraft, and they usually have their wings held in place
> with nylon bolts, and to keep them flexible, and less brittle you should
> cook them at least once a season - could the same help for a rotomoulded
> kayak?
>
> Tord
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From: Bob Carter <revkayak_at_aptalaska.net>
subject: Re: [Paddlewise] boiling kayaks
Date: Mon, 4 Dec 2006 20:17:57 -0900
 you should cook them at least once a season - could the same help for a 
rotomoulded kayak?

I find boiling things makes food taste bland.
What seasonings do you recommend?
What about geography? Cayan pepper seasoning for boats paddled in Mexico and 
seal oil for boats up here in Alaska?
Do you boil ruddered kayaks longer or the same amount of time as a boat with 
a skeg?

Just curious
Bob
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From: Craig Jungers <crjungers_at_gmail.com>
subject: Re: [Paddlewise] boiling kayaks
Date: Mon, 4 Dec 2006 23:36:22 -0800
On 12/4/06, Bob Carter <revkayak_at_aptalaska.net> wrote:
>
>
> Do you boil ruddered kayaks longer or the same amount of time as a boat
> with a skeg?



Bob... always remove the rudders and skegs; if you can't fit them into your
mouth sideways (on edge) then you shouldn't be eating kayaks. :)


Craig Jungers
Royal City, WA
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From: Bob Carter <revkayak_at_aptalaska.net>
subject: Re: [Paddlewise] boiling kayaks
Date: Tue, 5 Dec 2006 09:00:45 -0900
The rudders and skegs would serve as good tooth picks afterwasrds.

Bob
  ----- Original Message -----
  From: Craig Jungers
  To: Bob Carter
  Cc: paddlewise
  Sent: Monday, December 04, 2006 10:36 PM
  Subject: Re: [Paddlewise] boiling kayaks


  On 12/4/06, Bob Carter <revkayak_at_aptalaska.net> wrote:

    Do you boil ruddered kayaks longer or the same amount of time as a boat
with a skeg?


  Bob... always remove the rudders and skegs; if you can't fit them into your
mouth sideways (on edge) then you shouldn't be eating kayaks. :)


  Craig Jungers
  Royal City, WA
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From: Allan McLane <amcl_at_sover.net>
subject: Re: [Paddlewise] Tsunami 120 vs 145
Date: Mon, 04 Dec 2006 23:54:48 -0500
Somewhat talking through my hat here but I believe that nylon is miildly hygroscopic and derives some of its flexibility from the water-swelling. Dry it out and it probably becomes more brittle.

I'd take anything Mike Daly says on this over what I just wrote ;]

--allan

On Mon, 4 Dec 2006 21:08:41 -0500 (EST), mike dziobak wrote:

I would say no. PE nalgene bottles that I have filled with near boiling 
H2O on winter camping trips seem to become brittle and break after only a
short period of use. I have some training as a chemist but I don't see how
"cooking" a nylon bolt would keep in flexible unless nylon becomes work
hardened over time and cooking it anneals it.
-mike



> I fly some model aircraft, and they usually have their wings held in place
> with nylon bolts, and to keep them flexible, and less brittle you should
> cook them at least once a season - could the same help for a rotomoulded
> kayak?
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From: Michael Daly <mikedaly_at_magma.ca>
subject: Re: [Paddlewise] Tsunami 120 vs 145
Date: Tue, 05 Dec 2006 02:07:01 -0500
Allan McLane wrote:

> I'd take anything Mike Daly says on this over what I just wrote ;]

Dave's the chemist.  I'm out of my league on this one.

Mike
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From: Tord Eriksson <tord_at_tord.nu>
subject: Re: [Paddlewise] Tsunami 120 vs 145
Date: Tue, 5 Dec 2006 10:19:59 +0100
On Tuesday 05 December 2006 05:54, you wrote:
> Somewhat talking through my hat here but I believe that nylon is miildly
> hygroscopic and derives some of its flexibility from the water-swelling.
> Dry it out and it probably becomes more brittle.

Yeah, that's it! 

Had forgotten the reason why, but that's it!

Thanks,
Tord
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From: Dave Kruger <kdruger_at_pacifier.com>
subject: Re: [Paddlewise] Tsunami 120 vs 145
Date: Tue, 05 Dec 2006 00:54:10 -0800
mike dziobak wrote:
> I would say no. PE nalgene bottles that I have filled with near boiling 
> H2O on winter camping trips seem to become brittle and break after only a
> short period of use. I have some training as a chemist but I don't see how
> "cooking" a nylon bolt would keep in flexible unless nylon becomes work
> hardened over time and cooking it anneals it.

Time for me to chine in:  the "cooking" Tord refers to is boiling in water, 
really, and it is the water that does the job, not the heat, although 
heating hastens the hydration.  Nylon embrittles with time as it dries out. 
  Because it is a polyamide, and amide groups are attracted to water, 
"rehydrating" the nylon seems to prolong its lifetime.  I would not have 
known about this effect, except that a buddy has some nylon bolt-on blades 
for his gas-powered weed eater, which the manual says should be stored in 
water so they will remain supple.  The soaking reduces blade failure in use.

Most of us have experienced the stretching of nylon cordage used for tent 
and tarp tie-outs as it gets wet.  This is a variant of the same effect.

Soaking in water won't help rotomoulded boats ... they will die no matter 
how wet they get!

-- 
Dave Kruger
Astoria, OR
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From: Robert Livingston <bearboat2_at_comcast.net>
subject: Re: [Paddlewise] Heating Bottles
Date: Tue, 5 Dec 2006 11:08:43 -0800
I wonder if someone could confirm this experience about the Nalgene  
bottles and clarify the issues with the various bottle plastics.

I use the Lexan Nalgene bottles for the same purposes but do not have  
enough experience to know if this shortens their life. The data that  
Nalgene supplies implies that these bottles can deal with these  
temperatures.


On Dec 5, 2006, at 12:54 AM, Dave Kruger wrote:

>> I would say no. PE nalgene bottles that I have filled with near  
>> boiling H2O on winter camping trips seem to become brittle and  
>> break after only a
>> short period of use.
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From: Michael Daly <mikedaly_at_magma.ca>
subject: Re: [Paddlewise] Heating Bottles
Date: Tue, 05 Dec 2006 15:04:05 -0500
Robert Livingston wrote:
> I wonder if someone could confirm this experience about the Nalgene  
> bottles and clarify the issues with the various bottle plastics.

My only experience with the PE Nalgene bottles is that they become brittle over 
time regardless of what goes in them.  Whether hot water accelerates this is 
moot for me, since I gave up on these in favour of the polycarbonate (Lexan) 
versions.  Aside from embrittlement, the PE bottles make water taste yucky.

> The data that  
> Nalgene supplies implies that these bottles can deal with these  
> temperatures.

The only issue with the polycarbonate bottles and hot water is the leaching of 
(I forget the name) chemicals into the water.  Whether or not this represents an 
appreciable health risk was discussed a while back on this forum with several 
posters offering the opinion that it is a small risk.

Polycarbonate certainly can handle autoclave conditions without significant 
reductions in apparent material properties.  They can also handle freezing well 
- I know a lot of folks who put a Nalgene bottle nearly full of water in the 
freezer to provide cold water on a long hot day.  I haven't heard of one 
breaking due to ice expansion yet, but those I know make sure there's an air 
space in the bottle to take up some expansion.

Mike
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From: Shin SUGIYAMA <ssugiya_at_bio.nagoya-u.ac.jp>
subject: Re: [Paddlewise] Heating Bottles
Date: Wed, 6 Dec 2006 10:38:10 +0900
>>I wonder if someone could confirm this experience about the Nalgene 
>>bottles and clarify the issues with the various bottle plastics.
>
>Polycarbonate certainly can handle autoclave conditions without 
>significant reductions in apparent material properties.

Aging of polycarbonate is accelerated by boiling etc.
It can withstand autoclaving but there is  loss in mechanical strength so
Nalgene doesn't recommend use in centrifuges after "repeated" sterilization.
I don't use their water bottles but do use their stuff in the lab.

To what extent pouring boiling water into polycarbonate water bottles
reduces their strength is hard to estimate but it  does cause 
leaching (though apparently minimal)  and the formation of 
microcracks. If Nalgene says its safe to do then its probably not a 
real problem  and just something to be a little more careful about as 
long as you don't mind replacing your bottle after a while.

Shin




-- 
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From: Michael Daly <mikedaly_at_magma.ca>
subject: Re: [Paddlewise] Heating Bottles
Date: Tue, 05 Dec 2006 22:16:17 -0500
Shin SUGIYAMA wrote:

Good info to know, Shin san.

> and the formation of microcracks.

I've seen lots of fine cracks form over time but never noticed a significant 
loss of strength or stiffness in _normal_ use.  They certainly don't have the 
effect that the cracking in the PE versions do.


Mike
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From: Gary J. MacDonald <garyj_at_rogers.com>
subject: Re: [Paddlewise] Heating Bottles
Date: Tue, 05 Dec 2006 16:49:02 -0500
OK.  Lots of people have trouble sorting these out, and for those who get strayed:

1.  Nalgene is a brand name, not a type of bottle or a kind of plastic.
2.  Nalgene bottles come in Polyethylene (the classic white translucent ones).
3.  Nalgene bottles come in Polycarbonate AKA Lexan (the new rigid ones: 
transparent, first in smoke colour now in many colours).
==========
4.  I think the original Q was about the old white PE bottles (getting harder to 
find) not the rigid Lexan ones.  I do not know if they are affected by boiling, 
but I certainly doubt the new type PC/Lexan one are.

5.  I have 10-15 yr old PE bottles, some of which were frozen almost daily for 
years on end.  I don't notice the taste, and because they are a bit flexible I 
felt better about freezing them. I never worried about splitting them with ice 
expansion. It is only recently that one split in the freezer, after being filled 
under a block of ice already inside, which was then pushed against the top end, 
and pushe dthrough it by the expansion.

6.  I sometimes freeze the PC/Lexan bottles, but with cubes as a starter to 
limit the expansion of a single block freezing.  If I just put water in to 
freeze, I put only a little water in to start them off, and on a slant so 
expansion will push up the sides, and not straight outward.

7.  I cannot see how the PC/Lexan bottles could resist the pressures of a full 
bottle of water freezing and expanding.  I have burst all kinds of things over 
the years.

8.  Just so you know, I live on ice water the way some people live on coffee.

GaryJ
>>>I would say no. PE nalgene bottles that I have filled with near  
>>>boiling H2O on winter camping trips seem to become brittle and  
>>>break after only a
>>>short period of use.
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From: James <jimtibensky_at_fastmail.fm>
subject: Re: [Paddlewise] Nalgene Bottles
Date: Wed, 06 Dec 2006 10:24:30 -0600
For what it is worth, the youth group I do kayak trips with gives a
Nalgene bottle to each teen before each trip.  It gives them one good
water bottle and is a nice souvenir.  It is imprinted with the name of
the organization and with a list of Leave No Trace principles.

The LNT folks would not give their seal of approval if the bottles were
to be Lexan, they have to be PE because Lexan is not recyclable.

For the Green fanatics among us . . .



Jim Tibensky
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From: Geoff Jennings <geoff_at_texaskilonewton.com>
subject: RE: [Paddlewise] Nalgene Bottles
Date: Thu, 7 Dec 2006 08:34:37 -0800
> The LNT folks would not give their seal of approval if the bottles were
> to be Lexan, they have to be PE because Lexan is not recyclable.
> 
> For the Green fanatics among us . . .

Eh.  That's silly.   Lexan is tough and lasts forever.  To me that's more
important than recyclable.  And I try and be as green as possible.   There
are millions of recyclable cheap plastic bottles clogging landfills. 

I wish "greenies" would focus on buying less, and buying things that will
last forever (including styles).  That's going to do as much or more than
recycling ever will. 

g
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From: mike dziobak <mdziobak_at_mtu.edu>
subject: RE: [Paddlewise] Nalgene Bottles
Date: Thu, 7 Dec 2006 14:42:34 -0500 (EST)
>> The LNT folks would not give their seal of approval if the bottles were
>> to be Lexan, they have to be PE because Lexan is not recyclable.
>
> Eh.  That's silly.   Lexan is tough and lasts forever.  To me that's more
> important than recyclable.  And I try and be as green as possible.   There
> are millions of recyclable cheap plastic bottles clogging landfills.
>
> I wish "greenies" would focus on buying less, and buying things that will
> last forever (including styles).  That's going to do as much or more than
> recycling ever will.

I agree for the most part. But I find the PE tops on those Lexan wide
mouth bottles wear out pretty fast for me and begin to leak. I've resorted
to putting a rubber o-ring in the groove of the screw top cover but it
doesn't want to stay there especially with hot liquids.

My most favored bottles are the PET soda pop bottles especially the ones
with wide mouths like the 1.5 liter Nestea iced tea bottles available here
in the Azores. I like putting dry foods like rice and powder milk in them
and cram them in all the little voids in Mariner II on long trips. There's
something real nice about grabing a container like that out of the kayak
instead of struggling with a dry bag. They last forever but it's too bad
they do weird things when hot liquids are poored in them. Anyone else here
use those PET sode bottles?
-mike
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From: Michael Daly <mikedaly_at_magma.ca>
subject: Re: [Paddlewise] Nalgene Bottles
Date: Thu, 07 Dec 2006 14:52:42 -0500
Geoff Jennings wrote:

> Eh.  That's silly.   Lexan is tough and lasts forever.  To me that's more
> important than recyclable.

Why I wouldn't express it as strongly as you, there is merit to this.  I have 
Lexan bottles that are still usable after over 15 years and that represents 
about 3-4 recycled PE bottles each.  Reduction is better than recycling in 
general.

It is possible to recycle polycarbonate - it just is not as easily done as other 
plastics.

Mike
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From: Darryl <Darryl.Johnson_at_sympatico.ca>
subject: Re: [Paddlewise] Nalgene Bottles
Date: Thu, 07 Dec 2006 16:23:30 -0500
> Geoff Jennings wrote:
> 
> > Eh.  That's silly.   Lexan is tough and lasts forever.  To me that's more
> > important than recyclable.
> 
> Why I wouldn't express it as strongly as you, there is merit to this.  I have 
> Lexan bottles that are still usable after over 15 years and that represents 
> about 3-4 recycled PE bottles each.  Reduction is better than recycling in 
> general.
> 
> It is possible to recycle polycarbonate - it just is not as easily done as other 
> plastics.
> 
> Mike


I was chatting with one of the lads who heads up the garbage 
collection and recycling for the City of Ottawa the other day, and he 
mentioned to me that most plastics can only be recycled once or 
twice. After that, they end up in a landfill somewhere.

So, it would seem to me that getting something that last for a long 
time would be a lot better than getting something that can be 
recycled.

-- 
  Darryl
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From: Bob Carter <revkayak_at_aptalaska.net>
subject: Re: [Paddlewise] Tsunami 120 vs 145
Date: Tue, 5 Dec 2006 09:03:34 -0900
> Otherwise, it's going to one hell of a pot to get the kayak inside!
>
> -- 
>  Darryl


For us married folk all we have to do is go out and buy a new boat without 
telling our wives.  When she finds out we have plenty of hot water to work 
with.

Bob
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